209015
Palladium(II) acetylacetonate
99%
Sinónimos:
Palladium(II) 2,4-pentanedionate, Pd(acac)2
Iniciar sesión para ver los precios por organización y contrato.
Seleccione un Tamaño
Acerca de este artículo
Fórmula lineal:
Pd(C5H7O2)2
Número CAS:
Peso molecular:
304.64
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
237-859-8
Beilstein/REAXYS Number:
4136188
MDL number:
Servicio técnico
¿Necesita ayuda? Nuestro equipo de científicos experimentados está aquí para ayudarle.
Permítanos ayudarleServicio técnico
¿Necesita ayuda? Nuestro equipo de científicos experimentados está aquí para ayudarle.
Permítanos ayudarleInChI key
JKDRQYIYVJVOPF-FDGPNNRMSA-L
InChI
1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
SMILES string
CC(=O)\C=C(\C)O[Pd]O\C(C)=C/C(C)=O
assay
99%
form
powder
reaction suitability
core: aluminum, reagent type: catalyst
mp
200-251 °C (dec.)
Quality Level
¿Está buscando productos similares? Visita Guía de comparación de productos
Categorías relacionadas
General description
Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium.
Application
Palladium(II) acetylacetonate (Pd(acac)2) was used in the following studies:
- Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).
- Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.
- As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2
Clase de almacenamiento
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Elija entre una de las versiones más recientes:
¿Ya tiene este producto?
Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.
Nicolas Marion et al.
Accounts of chemical research, 41(11), 1440-1449 (2008-09-09)
Metal-catalyzed cross-coupling reactions, notably those permitting C-C bond formation, have witnessed a meteoritic development and are now routinely employed as a powerful synthetic tool both in academia and in industry. In this context, palladium is arguably the most studied transition
Sümeyra Diyarbakir et al.
ACS applied materials & interfaces, 7(5), 3199-3206 (2015-01-17)
Monodisperse CuPd alloy nanoparticles (NPs) were prepared by using a typical high-temperature organic solution phase protocol comprising the coreduction of copper(II) acetylacetonate and palladium(II) acetylacetonate by morpholine-borane complex in oleylamine and 1-octadecene solution at 80 °C. The presented synthesis protocol
Lukas J Goossen et al.
Journal of the American Chemical Society, 129(15), 4824-4833 (2007-03-23)
A new strategy for the regiospecific construction of unsymmetrical biaryls is presented, in which easily available salts of carboxylic acids are decarboxylated in situ to give arylmetal species that serve as the nucleophilic component in a catalytic cross-coupling reaction with
Sublimation and deposition behaviour of palladium (II) acetylacetonate.
Cominos V and Gavriilidis A.
The European Physical Journal - Applied Physics, 15(01), 23-33 (2001)
Paul Chatelain et al.
Angewandte Chemie (International ed. in English), 58(42), 14959-14963 (2019-08-24)
Ideal organic syntheses involve the rapid construction of C-C bonds, with minimal use of functional group interconversions. The Suzuki-Miyaura cross-coupling (SMC) is a powerful way to form biaryl linkages, but the relatively similar reactivity of electrophilic partners makes iterative syntheses
Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.
Póngase en contacto con el Servicio técnico