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Merck

221678

Raney®-Nickel

W.R. Grace and Co. Raney® 2800, slurry, in H2O, active catalyst

Sinónimos:

Raney Ni, Nickel sponge

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Fórmula lineal:
AlNi
Número CAS:
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
eCl@ss:
38190701
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Quality Level

form

slurry

composition

Ni, ≥89%

reaction suitability

core: nickel, reagent type: catalyst

manufacturer/tradename

W.R. Grace and Co. Raney® 2800

concentration

in H2O

impurities

6-9% Al

particle size

20-60 μm

pH

8.5-12.0

SMILES string

[Al].[Ni]

InChI

1S/Al.Ni

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

Application

Suitable as a hydrogenation catalyst for aromatic, olefin, nitrile and nitro group reductions.
Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.


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Danger

Hazard Classifications

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

Clase de almacenamiento

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable



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Cognizance of the mechanical properties of nickel-titanium archwires is necessary for the management of orthodontic therapy with fixed appliances. Acting on the periodontium with forces that are too heavy may lead to such complications as: pain, tooth root resorption and
Fariborz Amini et al.
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In this report, we present an uncomplicated approach to overcome lingual rolling of mandibular molars during orthodontic treatment, by using rectangular NiTi arch wire in twist fashion through the molar tube. The sequential steps of the twist manoeuvre on a