337528
Bromuro de alilo
reagent grade, 97%, contains ≤1000 ppm propylene oxide as stabilizer
Sinónimos:
3-Bromo-1-propeno
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Acerca de este artículo
Fórmula lineal:
CH2=CHCH2Br
Número CAS:
Peso molecular:
120.98
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-446-6
Beilstein/REAXYS Number:
605308
MDL number:
Assay:
97%
Form:
liquid
Servicio técnico
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reagent grade
Quality Level
vapor density
4.2 (vs air)
assay
97%
form
liquid
autoignition temp.
554 °F
contains
≤1000 ppm propylene oxide as stabilizer
expl. lim.
7.3 %
refractive index
n20/D 1.469 (lit.)
bp
70-71 °C (lit.)
mp
−119 °C (lit.)
density
1.398 g/mL at 25 °C (lit.)
functional group
alkyl halide, bromo
storage temp.
2-8°C
SMILES string
BrCC=C
InChI
1S/C3H5Br/c1-2-3-4/h2H,1,3H2
InChI key
BHELZAPQIKSEDF-UHFFFAOYSA-N
Application
Allyl bromide can be used:
- For the synthesis of stereodefined allylated arenes via Suzuki-type coupling reaction.
- In Barbier-type allylation reactions of aldehydes and ketones.{17]
- To synthesize a monomer, 1-1-(allyloxy)-4-nitrobenzene while synthesizing nanostructured molecularly imprinted polymer for selective tryptophan assay in biological and pharmaceutical samples.
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Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B
Clase de almacenamiento
3 - Flammable liquids
flash_point_f
30.2 °F - closed cup
flash_point_c
-1 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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A tryptophan assay based on the glassy carbon electrode modified with a nano-sized tryptophan-imprinted polymer and multi-walled carbon nanotubes
Alizadeh T and Amjadi S
New. J. Chem., 41(11), 4493-4502 (2017)
Catalyst-Free Suzuki-Type Coupling of Allylic Bromides with Arylboronic Acids
Scrivanti A, et al.
European Journal of Organic Chemistry, 2012(2), 264-268 (2012)
Terra D Haddad et al.
The Journal of organic chemistry, 75(3), 642-649 (2009-12-24)
We report a simple, efficient, and general method for the indium-mediated enantioselective allylation of aromatic and aliphatic aldehydes and ketones under Barbier-type conditions in a one-pot synthesis affording the corresponding chiral alcohol products in very good yield (up to 99%)