429414
Indium(III) chloride
anhydrous, powder, ≥99.999% trace metals basis
Sinónimos:
Trichloroindigane, Indium trichloride
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Fórmula lineal:
InCl3
Número CAS:
Peso molecular:
221.18
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-043-0
MDL number:
Assay:
≥99.999% trace metals basis
Grade:
anhydrous
Form:
powder
Servicio técnico
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Permítanos ayudarlegrade
anhydrous
assay
≥99.999% trace metals basis
form
powder
reaction suitability
core: indium, reagent type: catalyst
impurities
<100 ppm H2O
density
3.46 g/mL at 25 °C (lit.)
application(s)
electroplating
material synthesis precursor
SMILES string
Cl[In](Cl)Cl
InChI
1S/3ClH.In/h3*1H;/q;;;+3/p-3
InChI key
PSCMQHVBLHHWTO-UHFFFAOYSA-K
General description
InCl3 is an efficient water-stable Lewis acid catalyst used in many organic transformations. It is moderately toxic and shows high tolerance to most of the oxygen and nitrogen containing functional groups. Owing to its optoelectronic properties it is also used to prepare many semiconductor materials.
Application
Indium(lll) chloride can be used as a catalyst to synthesize:
- Indolylindolines through self-addition of indoles.
- Vinyl indoles from unfunctionalized indoles and vinyl azides.
- Variety of cycloadducts through the reaction of olefinic acetals with isoprene and cyclopentadiene.
- N-tosylimines through a condensation reaction of aldehydes with p-toluenesulfonamide.
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C - STOT RE 1 Inhalation
target_organs
Lungs
Clase de almacenamiento
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Mechanisms of synthesis reaction of pure anhydrous indium(III) chloride
Wieslaw Gawel and Tomasz Kloc and Igor Mucha
Inorganica chimica acta, 495, 118991-118991 (2019)
Efficient and convenient preparation of N-tosylimines catalyzed by indium trichloride
Gui Sheng Deng et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 22(5), 511-514 (2011)
First indium trichloride catalyzed self-addition of indoles: One pot synthesis of indolylindolines
Bikash Pal, et al.
Catalysis Communications, 6(11), 711-715 (2005)