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Merck

938777

Cesium carbonate ChemBeads

solid

Sinónimos:

Carbonic acid dicesium ChemBeads

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Fórmula empírica (notación de Hill):
Cs2CO3
Peso molecular:
325.82
UNSPSC Code:
12352100
NACRES:
NA.21
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Nombre del producto

Cesium carbonate ChemBeads,

Quality Level

product line

ChemBeads

form

solid

pH

14-16(loading of base)

SMILES string

O=COO[Cs].[Cs]

InChI

1S/CH2O3.2Cs/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

FJDQFPXHSGXQBY-UHFFFAOYSA-L

General description

Cesium carbonate is a powerful inorganic base widely used in organic synthesis. It is a potential chemoselective catalyst for the reduction of aldehydes and ketones to alcohols. It is employed as base for the Heck coupling reaction of 4-trifluoromethyl-1-chlorobenzene and aryl chlorides.

Application

Cesium carbonate can be used as a base in C-C and C-N cross-coupling reactions such as Suzuki−Miyaura, Heck, and Buchwald-Hartwig amination reactions. It is also used as a base in alkylation reactions. Promotes the efficient O-alkylation of alcohols to form mixed alkyl carbonates.

For general uses, product is also available in powdered form(441902)

Features and Benefits

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.


pictograms

Health hazardCorrosion

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Repr. 2 - STOT RE 2 Oral

target_organs

Kidney,Adrenal gland,Testes

Clase de almacenamiento

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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