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843873 Lithium bis(trifluoromethanesulfonyl)imide

Lithium bis(trifluoromethanesulfonyl)imide for synthesis. CAS 90076-65-6, pH 6.0 - 8.0 (100 g/l, H₂O, 20 °C).

Lithium bis(trifluoromethanesulfonyl)imide MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.
CAS #: 90076-65-6 EC Number: 415-300-0 Molar Mass: 287.08 g/mol Hill Formula: C₂F₆LiNO₄S₂
843873
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Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
90076-65-6415-300-0C₂F₆LiNO₄S₂287.08 g/mol
Description
Catalogue Number843873
References
Product Information
CAS number90076-65-6
EC index number616-124-00-9
EC number415-300-0
Hill FormulaC₂F₆LiNO₄S₂
Molar Mass287.08 g/mol
HS Code2935 90 99
Structure formula ImageStructure formula Image
Quality LevelMQ200
Applications
ApplicationLithium bis(trifluoromethanesulfonyl)imide for synthesis. CAS 90076-65-6, pH 6.0 - 8.0 (100 g/l, H₂O, 20 °C).
Biological Information
Physicochemical Information
Density2.15 g/cm3 (20 °C)
Ignition temperature>420 °C
Melting Point233 °C
pH value7.0 - 9.5 (10 g/l, H₂O)
Vapor pressure<0.000001 hPa (25 °C)
Dimensions
Materials Information
Toxicological Information
LD 50 oralLD50 Rat 160 mg/kg
Safety Information according to GHS
Hazard Pictogram(s) Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Pictogram(s)
Hazard Statement(s)H301 + H311: Toxic if swallowed or in contact with skin.
H314: Causes severe skin burns and eye damage.
H373: May cause damage to organs through prolonged or repeated exposure if swallowed.
H412: Harmful to aquatic life with long lasting effects.
Precautionary Statement(s)P260: Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal WordDanger
Storage class6.1B Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3 highly hazardous to water
Disposal26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
Safety Information
Categories of dangertoxic, corrosive, dangerous for the environment
Product Usage Statements
Storage and Shipping Information
StorageStore below +30°C.
Packaging Information
Transport Information
Declaration (railroad and road) ADR, RIDUN 2923 , 8 (6.1), II
Declaration (transport by air) IATA-DGRUN 2923 , 8 (6.1), II
Declaration (transport by sea) IMDG-CodeUN 2923 , 8 (6.1), II
Supplemental Information
Specifications
Assay (alkalimetric after ionic exchange)≥ 98.0 %
Identity (IR)passes test