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New: 848335  Bio-Methanol (Gas-to-Liquid)
for synthesis

For general questions please contact our Customer Service:

Merck KGaA
Frankfurter Str. 250
64293 Darmstadt
Germany
Phone: +49 6151 72-0
Fax: +49 6151 72 2000

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25 May 2012

loading
 
Product number Packaging Qty/Pk
8483359050  Barrel PE/met  50 l 
Product information
Hill Formula CH4O
Chemical formula CH3OH
HS Code 2905 11 00
EC number 200-659-6
Molar mass 32.04 g/mol
EC index number 603-001-00-X
CAS number 67-56-1
Chemical and physical data
Ignition temperature 455 °C DIN 51794
Solubility (20 °C) soluble
Melting point -98 °C
Molar mass 32.04 g/mol
Density 0.792 g/cm3 (20 °C)
pH value (H2O) no data available
Boiling point 64.5 °C (1013 hPa)
Vapor pressure 128 hPa (20 °C)
Explosion limit 5.5 - 44 %(V)
Flash point 10 °C
Refractive index 1.33
Water absorption 1000 g/kg
Evaporation number 6.3
Safety information according to GHS
Hazard Statement(s) H225: Highly flammable liquid and vapour.
H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled
H370: Causes damage to organs.
Precautionary Statement(s) P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280: Wear protective gloves/ protective clothing.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P403 + P235: Store in a well-ventilated place. Keep cool.
Signal Word Danger
Hazard Pictogram(s)
RTECS PC1400000
Storage class 3 Flammable liquids
WGK WGK 1 slightly water endangering
Disposal 1
Strongly contaminated halogen-free organic solvents: container A.
Safety information
R Phrase R 11-23/24/25-39/23/24/25
Highly flammable.Toxic by inhalation, in contact with skin and if swallowed.Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
S Phrase S 7-16-36/37-45
Keep container tightly closed.Keep away from sources of ignition - No smoking.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Categories of danger highly flammable, toxic
Hazard Symbol
Flammable
Toxic
Transport information
Declaration (railroad and road) ADR, RID UN 1230 Methanol, 3 (6.1), II
Declaration (transport by sea) IMDG-Code UN 1230 METHANOL, 3 (6.1), II
Declaration (transport by air) IATA-DGR UN 1230 METHANOL, 3 (6.1), II
Toxicological data
LD 50 oral LD50 rat 5628 mg/kg
LD 50 dermal LD50 rabbit 17100 mg/kg

© Merck KGaA, Darmstadt, Germany, 2012


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