225916
Benzylmagnesium chloride solution
2.0 M in THF
Synonyme(s) :
(Phenylmethyl)magnesium chloride, Benzylchloromagnesium, Chloro(phenylmethyl)magnesium
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A propos de cet article
Formule linéaire :
C6H5CH2MgCl
Numéro CAS:
Poids moléculaire :
150.89
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
878506
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reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
2.0 M in THF
density
1.031 g/mL at 25 °C
functional group
phenyl
SMILES string
Cl[Mg]Cc1ccccc1
InChI
1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
InChI key
NRAFPLGJPPJUNB-UHFFFAOYSA-M
General description
Benzylmagnesium chloride is an organometallic compound that acts as a Lewis acid and a strong base.
Application
Benzylmagnesium chloride (Grignard reagent) can be used as an alkylating reagent:
- For alkylating quinolyl-functionalized Cp−chromium(III) complexes which are used as precursors for the preparation of active olefin polymerization catalysts.
- In the synthesis of 2,3-disubstituted benzopyran-4-ones, 6-chloro-8-methylpurine derivative, and phenylalanine derivatives.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Classe de stockage
3 - Flammable liquids
wgk
WGK 2
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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A facile three-step synthesis of 1, 2-amino alcohols using the Ellman homochiral tert-butylsulfinamide
Barrow JC, et al.
Tetrahedron Letters, 42(11), 2051-2054 (2001)
A novel synthesis of 2, 3-disubstituted benzopyran-4-ones and application to the solid phase
Harikrishnan LS and Showalter HD H
Tetrahedron, 56(4), 515-519 (2000)
Quinolyl-functionalised Cp-chromium polymerisation catalysts: synthesis and crystal structures of alkylation products
Enders M, et al.
Journal of Organometallic Chemistry, 687(1), 125-130 (2003)