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Merck

577030

Polypyrrole

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conductivity 10-50 S/cm (pressed pellet)

Synonyme(s) :

PPy

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A propos de cet article

Numéro CAS:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
MDL number:
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SMILES string

[nH]1cccc1

InChI

1S/C4H5N/c1-2-4-5-3-1/h1-5H

InChI key

KAESVJOAVNADME-UHFFFAOYSA-N

description

Electrodes

form

solid

contains

proprietary organic sulfonic acid as dopant

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solubility

H2O: insoluble, organic solvents: insoluble

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Quality Level

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General description

Polypyrrole (PPy) is a widely used highly conductive and highly stable heterocyclic polymer. It is majorly used in electrochemical applications. It is a cost-efficient conducting polymer that has a stable oxidation and high solubility in water. It exhibits a high degree of flexibility than polyaniline and has a density that facilitates a higher capacitance per unit volume.
PPy may be prepared by a standard electrochemical technique. It may also be prepared by reacting -napthalene sulfonic acid (NSA) and ammonium peroxo-disulfate in aqueous medium. The charges on the surfaces can be easily modified by doping the polymer during its synthesis. Solubility and conductivity measurements of PPy doped with camphor sulfonic and dodecyl benzene sulfonic acid have been reported. Lectrosensitivity and lower oxidation potential of PPy make it potentially useful for drug delivery, chemical sensors, batteries, ion selective electrodes, biosensor and biochemistry research.
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Application

Conducting polymer.
Conductive additive for thermoplasitics and thermosets.
Conductive additive for thermoplastics and thermosets. Polypropylene composites constitute the polymer electrolyte membrane fuel cell (PEMFC). Addition of PPy to polypropylene composites alters its conductivity.
PPy can be used for a variety of applications such as:
  • electrode materials for sensors used in electrocardiography (ECG)
  • formation of electrode material for a variety of energy storage applications
  • encapsulation of lithium sulfide (Li2S) as a high performance cathode material

PPy is mainly used in the fabrication of a variety of electrochemical devices, which include supercapacitors, chemical sensors, dye sensitized solar cells and lithium-ion batteries.

Packaging

Packaged in glass bottles

Other Notes

Stable up to at least 290°C in air

Classe de stockage

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Consulter la Bibliothèque de documents

Conducting polymers with superhydrophobic effects as anticorrosion coating
Intelligent Coatings for Corrosion Control, 409-430 (2014)
In-situ encapsulation of nickel nanoparticles in polypyrrole nanofibres with enhanced performance for supercapacitor
Muhamad SU, et al.
Electrochimica Acta, 249(8), 9-15 (2017)
Sensors Based on Conducting Polymers for Measurement of Physiological Parameters
Teran-Jimenez O, et al.
IEEE Sensors Journal, 17(8), 2492-2497 (2017)
Electrochemistry of nucleic acids and proteins: towards electrochemical sensors for genomics and proteomics
Palecek E, et al.
Journal of Nanoscience and Nanotechnology, 1(1), 596-612 (2005)
Facile synthesis of Li 2 S-polypyrrole composite structures for high-performance Li 2 S cathodes
She ZW, et al.
Energy & Environmental Science, 7(2), 672-676 (2014)

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