751855
Hydrazine solution
1 M in acetonitrile
Synonyme(s) :
Hydrazine, Nitrogen hydride
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A propos de cet article
Formule linéaire :
NH2NH2
Numéro CAS:
Poids moléculaire :
32.05
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
878137
Form:
liquid
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OAKJQQAXSVQMHS-UHFFFAOYSA-N
SMILES string
NN
InChI
1S/H4N2/c1-2/h1-2H2
form
liquid
concentration
1 M in acetonitrile
refractive index
n20/D 1.348
density
0.779 g/mL at 25 °C
functional group
hydrazine
Quality Level
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Catégories apparentées
General description
Hydrazine (N2H4) solution is a common reducing agent and a versatile reagent in organic synthesis. It can reduce a variety of functional groups like ketones, aldehydes, imines, nitro compounds, azides & nitrates to their corresponding amines. It also serves as a source of nitrogen in the synthesis of heterocyclic compounds, such as pyrazoles and pyrazolines.
Application
Hydrazine solution (in acetonitrile) can be used as a reducing source for the reduction of carbon-carbon multiple bonds in alkenes, alkynes, and α,β-unsaturated esters using metal-organic frameworks (MOFs) as heterogeneous catalysts. It is also used in the synthesis of polysubstituted 2-aminoimidazoles from 2-aminopyrimidines and α-bromocarbonyl compounds.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1
Classe de stockage
3 - Flammable liquids
wgk
WGK 3
flash_point_f
41.0 °F
flash_point_c
5 °C
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M Vogel et al.
Fresenius' journal of analytical chemistry, 366(8), 781-791 (2001-03-03)
Hydrazine reagents are a well-known group of derivatizing agents for the determination of aldehydes and ketones in liquid and gaseous samples. Within this article, the most important hydrazine reagents are critically summarized, and their major applications in different fields, including
Nilay Hazari
Chemical Society reviews, 39(11), 4044-4056 (2010-06-24)
One of the most challenging problems in small molecule activation is the development of a homogeneous catalyst for converting dinitrogen into ammonia at ambient temperatures and atmospheric pressure. A catalytic cycle based on molybdenum that converts dinitrogen into ammonia has
D P Elder et al.
Journal of pharmaceutical and biomedical analysis, 54(5), 900-910 (2010-12-15)
This is the latest of a series of reviews focused on the analysis of genotoxic impurities. This review summarises the analytical approaches reported in the literature relating to hydrazine, hydrazines, hydrazides and hydrazones. It is intended to provide guidance for
Min Yuan et al.
Dalton transactions (Cambridge, England : 2003), (31)(31), 6078-6088 (2010-05-08)
A combination of unique solvent properties of hydrazine enables the direct dissolution of a range of metal chalcogenides at ambient temperature, rendering this an extraordinarily simple and soft synthetic approach to prepare new metal chalcogenide-based materials. The extended metal chalcogenide
Yinhu Wang et al.
Biosensors & bioelectronics, 43, 180-185 (2013-01-12)
We report a novel hydrogen peroxide (H2O2) and hydrazine sensor based on low-cost poly(vinylpyrrolidone)-protected silver nanocubes (PVP-AgNCs). The monodisperse silver nanocubes were prepared by adding a trace amount of sodium sulfide in the conventional polyol synthesis for fast reduction of
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