296295
Anisole
anhydrous, 99.7%
Synonyme(s) :
Methoxybenzene, Methyl phenyl ether
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A propos de cet article
Formule linéaire :
CH3OC6H5
Numéro CAS:
Poids moléculaire :
108.14
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
39023603
UNSPSC Code:
12352112
EC Number:
202-876-1
MDL number:
Beilstein/REAXYS Number:
506892
Assay:
99.7%
Grade:
anhydrous
Bp:
154 °C (lit.)
Vapor pressure:
10 mmHg ( 42.2 °C)
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anhydrous
Quality Level
vapor density
3.7 (vs air)
vapor pressure
10 mmHg ( 42.2 °C)
assay
99.7%
form
liquid
autoignition temp.
887 °F
expl. lim.
8 %
impurities
<0.002% water, <0.005% water (100 mL pkg)
evapn. residue
<0.0003%
refractive index
n20/D 1.516 (lit.)
bp
154 °C (lit.)
mp
−37 °C (lit.)
density
0.995 g/mL at 25 °C (lit.)
SMILES string
COc1ccccc1
InChI
1S/C7H8O/c1-8-7-5-3-2-4-6-7/h2-6H,1H3
InChI key
RDOXTESZEPMUJZ-UHFFFAOYSA-N
Application
Anisole may undergo:
It may also be used as a surrogate for lignin primary tar in pyrolysis experiments.
- Zeolite-catalyzed Friedel-Crafts acylation with acetic anhydride in acetic acid to form 4-methoxyacetophenone with high selectivity.
- Bismuth triflate-catalyzed Friedel-Crafts benzoylation with benzoic anhydride to form 4-methoxybenzophenone under solvent-free microwave irradiation.
It may also be used as a surrogate for lignin primary tar in pyrolysis experiments.
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signalword
Warning
hcodes
Hazard Classifications
Flam. Liq. 3 - STOT SE 3
target_organs
Central nervous system
Classe de stockage
3 - Flammable liquids
flash_point_f
125.1 °F - closed cup
flash_point_c
51.7 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Selective vapor-phase hydrodeoxygenation of anisole to benzene on molybdenum carbide catalysts.
Lee WS, et al.
J. Catal., 319, 44-53 (2014)
A Novel Friedel-Crafts Acylation Reaction of Anisole for Production of 4-Methoxyacetophenone with High Selectivity and Sufficient Reusability of Mordenite Zeolite Catalyst
Makihara M & Komura K
Green and Sustainable Chemistry, 7(03), 185-185 (2017)
Vibrational spectra and torsional barriers of anisole and some monohalogen derivatives.
Owen NL and Hester RE.
Spectrochimica Acta Part A: Molecular Spectroscopy, 25(2), 343-354 (1969)