456756
Iodométhane solution
2.0 M in tert-butyl methyl ether, solution, contains copper as stabilizer
Synonyme(s) :
Iodure de méthyle
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A propos de cet article
Formule empirique (notation de Hill) :
CH3I
Numéro CAS:
Poids moléculaire :
141.94
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Beilstein/REAXYS Number:
969135
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Laissez-nous vous aiderNom du produit
Iodométhane solution, 2.0 M in tert-butyl methyl ether, contains copper as stabilizer
InChI key
INQOMBQAUSQDDS-UHFFFAOYSA-N
SMILES string
CI
InChI
1S/CH3I/c1-2/h1H3
vapor pressure
16.85 psi ( 55 °C)
4.86 psi ( 20 °C)
contains
copper as stabilizer
concentration
2.0 M in tert-butyl methyl ether
bp
41-43 °C
density
0.933 g/mL at 25 °C
functional group
alkyl halide
iodo
storage temp.
2-8°C
Quality Level
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Catégories apparentées
Application
- 8-plex LC-MS/MS Analysis of Permethylated N-Glycans Achieved by Using Stable Isotopic Iodomethane.: This research demonstrates the use of iodomethane in stable isotope labeling for the mass spectrometric analysis of permethylated N-glycans. The method enhances the accuracy and sensitivity of glycomic studies (Dong et al., 2019).
- Comparative glycomic profiling of isotopically permethylated N-glycans by liquid chromatography/electrospray ionization mass spectrometry.: The study presents a comparative analysis of N-glycan profiles using isotopically labeled iodomethane, improving the resolution and identification of glycan structures in complex biological samples (Hu et al., 2013).
- Antifungal property of quaternized chitosan and its derivatives.: This paper explores the synthesis of quaternized chitosan derivatives using iodomethane and their subsequent antifungal activities. The results suggest potential applications in biomedical and agricultural fields (Sajomsang et al., 2012).
- Validation of two fluoro-analogues of N,N-dimethyl-2-(2′-amino-4′-hydroxymethyl-phenylthio)benzylamine as serotonin transporter imaging agents using microPET.: This research validates fluoro-analogues of a serotonin transporter imaging agent, synthesized using iodomethane, highlighting its potential in neuroimaging applications (Jarkas et al., 2010).
General description
The product is 2M solution of iodomethane in tert-butyl methyl ether. Iodomethane also known as methyl iodide is an alkyl halide commonly employed as methylating agent.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2
Classe de stockage
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-0.4 °F
flash_point_c
-18 °C
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Microhydration effects on the intermediates of the S(N)2 reaction of iodide anion with methyl iodide.
Keisuke Doi et al.
Angewandte Chemie (International ed. in English), 52(16), 4380-4383 (2013-01-31)
R Otto et al.
Nature chemistry, 4(7), 534-538 (2012-06-22)
Solvents have a profound influence on chemical reactions in solution and have long been used to control their outcome. Such effects are generally considered to be governed by thermodynamics; however, little is known about the steric effects of solvent molecules.
Christian R Evenhuis et al.
The journal of physical chemistry. A, 115(23), 5992-6001 (2011-02-12)
The photodissociation of methyl iodide in the A band is studied by full-dimensional (9D) wave packet dynamics calculations using the multiconfigurational time-dependent Hartree approach. The potential energy surfaces employed are based on the diabatic potentials of Xie et al. [J.
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