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Merck

215996

Ammonium phosphate dibasic

ACS reagent, ≥98%

Synonyme(s) :

Ammonium hydrogenphosphate, Diammonium hydrogenphosphate, di-Ammonium hydrogenphosphate (sec)

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A propos de cet article

Formule linéaire :
(NH4)2HPO4
Numéro CAS:
Poids moléculaire :
132.06
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
231-987-8
MDL number:
Assay:
≥98%
Grade:
ACS reagent
Form:
powder, crystals or chunks
Service technique
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grade

ACS reagent

Quality Level

assay

≥98%

form

powder, crystals or chunks

impurities

≤0.005% NH4OH pptd., ≤0.005% insolubles

pH

7.7-8.1 (25 °C, 5%)

mp

155 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤0.001%, nitrate (NO3-): ≤0.003%, sulfate (SO42-): ≤0.01%

cation traces

Ca: 0.001%, Fe: ≤0.001%, K: ≤0.005%, Mg: 0.0005%, Na: ≤0.005%, heavy metals (as Pb): ≤0.001%

SMILES string

N.N.OP(O)(O)=O

InChI

1S/2H3N.H3O4P/c;;1-5(2,3)4/h2*1H3;(H3,1,2,3,4)

InChI key

MNNHAPBLZZVQHP-UHFFFAOYSA-N

General description

Ammonium phosphate dibasic is a water-soluble ammonium phosphate salt. It is a key component of phosphate fertilizers. It is commonly used as a flame retardant for plywood, paper, and fabrics, as well as a corrosion inhibitor consolidant for degraded carbonatic materials found in old buildings.

Application

Ammonium phosphate dibasic can be used as a catalyst:
  • To synthesize tetrahydrobenzo[b]pyranderivatives via three‐component condensation reaction.
  • In the solvent-free Biginelli reactions.
  • To synthesize bis(indolyl)methanes via solvent-free reaction of indole derivatives and aromatic or aliphatic aldehydes.


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Classe de stockage

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



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Consulter la Bibliothèque de documents



Ash M and Ash I.
Handbook of Green Chemicals, 627-627 (2004)
Matteo Frasnelli et al.
Acta biomaterialia, 33, 283-289 (2016-01-23)
The beta to alpha transition in tricalcium phosphate (TCP) bioceramics containing different amount of magnesium was studied in the present work. Mg-doped TCP powder was obtained by solid-state reaction starting from pure calcium carbonate, ammonium phosphate dibasic and magnesium oxide
Diammonium hydrogenphosphate for the consolidation of building materials. Investigation of newly-formed calcium phosphates.
Elena P, et al.
Construction Building Materials, 195, 557-563 (2019)