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Merck

243973

Sodium bisulfite

ACS reagent

Synonyme(s) :

Sodium hydrogensulfite

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A propos de cet article

Formule empirique (notation de Hill) :
NaHSO3
Numéro CAS:
Poids moléculaire :
104.06
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21
Grade:
ACS reagent
Form:
powder or crystals
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SMILES string

[Na+].OS([O-])=O

InChI

1S/Na.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+1;/p-2

InChI key

DWAQJAXMDSEUJJ-UHFFFAOYSA-L

grade

ACS reagent

form

powder or crystals

concentration

≥58.5% SO2

impurities

≤0.005% insolubles

pH

4.3 (10 g/L)

anion traces

chloride (Cl-): ≤0.02%

cation traces

Fe: ≤0.002%, heavy metals (as Pb): ≤0.001%

Quality Level

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Catégories apparentées

General description

Sodium bisulfite is a widely used industrial chemical as a reducing agent, catalyst, and preservative in pharmaceuticals and foods due to its antioxidative and antibacterial effects.
The aqueous solutions of sodium bisulfite are acidic in nature. Degradation of sodium bisulfite with acid forms sulfur dioxide gas.

Application

Sodium bisulfite (NaHSO3) has been used as a reagent to compose the immunoprecipitation (IP) buffer to chemically modify DNA and to synthesize arsenolipids (AsL).
It can also be used as a reagent during the synthesis of 5,6-dihydrouracil-6-sulfonate.
Sodium bisulfite can be used as:
  • A reagent to synthesize aldehyde-bisulfite adducts from aromatic and aliphatic aldehydes.
  • A catalyst in the solvent-free etherification of aromatic/aliphatic alcohols to synthesize symmetric and unsymmetric ethers via intermolecular dehydration.
  • An additive in the copper-catalyzed homocoupling of ketoxime carboxylates to synthesize symmetrical pyrroles.

Disclaimer

The product is not intendedfor use as a biocide under global biocide regulations, including but notlimited to the US EPA′s Federal Insecticide Fungicide and Rodenticide Act, theEuropean Biocidal Products Regulation, Canada’s Pest Management RegulatoryAgency, Turkey’s Biocidal Products Regulation, Korea’s Consumer ChemicalProducts and Biocide Safety Management Act (K-BPR), and others.

pictograms

Exclamation mark

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Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

supp_hazards

Classe de stockage

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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Consulter la Bibliothèque de documents

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Ledgard J.
The Preparatory Manual of Explosives., 87-87 (2007)
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Journal of Korean medical science, 24(1), 97-103 (2009-03-10)
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Katja Biewusch et al.
Methods in molecular biology (Clifton, N.J.), 863, 273-280 (2012-02-24)
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