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Merck

360511

4-Methyl-2-pentanone

ACS reagent, ≥98.5%

Synonyme(s) :

Isobutyl methyl ketone, Isopropylacetone, MIBK, Methyl isobutyl ketone

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A propos de cet article

Formule linéaire :
(CH3)2CHCH2COCH3
Numéro CAS:
Poids moléculaire :
100.16
UNSPSC Code:
12352115
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-550-1
Beilstein/REAXYS Number:
605399
MDL number:
Assay:
≥98.5%
Grade:
ACS reagent
Bp:
117-118 °C
Vapor pressure:
15.7 mmHg ( 20 °C)
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InChI key

NTIZESTWPVYFNL-UHFFFAOYSA-N

InChI

1S/C6H12O/c1-5(2)4-6(3)7/h5H,4H2,1-3H3

SMILES string

CC(C)CC(C)=O

grade

ACS reagent

vapor density

3.5 (vs air)

vapor pressure

15.7 mmHg ( 20 °C)

assay

≥98.5%

form

liquid

autoignition temp.

840 °F

expl. lim.

1.2-8 %, 93 °F

dilution

(for analytical testing)

impurities

≤0.002 meq/g Titr. acid, ≤0.100% water

evapn. residue

≤0.0050%

color

APHA: ≤15, clear

refractive index

n20/D 1.395 (lit.)

Quality Level

bp

117-118 °C

mp

−80 °C (lit.)

density

0.801 g/mL at 25 °C (lit.)

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General description

4-Methyl-2-pentanone (Methyl isobutyl ketone (MIBK)) is an organic solvent widely used in various industrial applications. It is used as a solvent for gums, resins, paints, varnishes, lacquers, and nitrocellulose. It is also used as a denaturant and solvent in cosmetic products.
Our premium ACS solvents are ideal for routine chemical synthesis, drying, purification, and critical labware cleaning. They meet or exceed the rigorous standards of the American Chemical Society (ACS), ensuring high-quality results for your research needs.

Premium ACS Solvents: Our solvents meet or exceed the stringent standards set by the American Chemical Society, ensuring high quality and reliability for your laboratory applications.

Replicable and Publishable Results: Designed for consistency, our solvents deliver results that can be reliably reproduced, making them ideal for research that requires publication.

Versatile Applications: Suitable for routine chemical synthesis, drying, purification, and critical labware cleaning, our solvents cater to a wide range of research needs in the laboratory.

Application

4-Methyl-2-pentanone is used:
  • To prepare (R)-(-)-4-methyl-2-pentanol via asymmetric hydrogenation in the presence of silica-supported starch-polysulfosiloxane-platinum complex (SiO2-ST-Si-S-Pt).
  • In the preparation of jet-fuel-range alkene [C10 and C11 branched alkanes] via aldol condensation reaction with furfural followed by hydrodeoxygenation reaction.
  • Extracting agent for silver, gold and other rare elements from cyanide solutions.

Features and Benefits

4-Methyl-2-pentanone or Methyl isobutyl ketone (MIBK) commonly used diluent or extractant due to its,
  • Low density
  • Viscosity.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Carc. 2 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

supp_hazards

Classe de stockage

3 - Flammable liquids

wgk

WGK 1

flash_point_f

57.2 °F - closed cup

flash_point_c

14 °C - closed cup


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Consulter la Bibliothèque de documents

Ginette Truchon et al.
Journal of occupational and environmental hygiene, 3(3), 137-143 (2006-02-09)
Compartmental and physiologically based toxicokinetic modeling coupled with Monte Carlo simulation were used to quantify the impact of biological variability (physiological, biochemical, and anatomic parameters) on the values of a series of bio-indicators of metal and organic industrial chemical exposures.
Jose Ruiz-Jimenez et al.
Journal of chromatography. A, 1616, 460825-460825 (2020-01-12)
Several calibration approaches were evaluated for the quantitation of volatile organic compounds in air using miniaturized exhaustive and non-exhaustive sampling techniques, such as in-tube extraction (ITEX) and solid phase microextraction (SPME) Arrow. Eleven compounds, 2-ethyl-hexanol, hexanal, nonanal, toluene, ethyl-benzene, methyl
H J Shim et al.
Journal of chromatography. B, Biomedical applications, 656(2), 407-414 (1994-06-17)
A high-performance liquid chromatographic method was developed for the simultaneous determination of a new anthracycline, DA-125 (I), and its metabolites (M1, M2, M3, and M4) in rat plasma and urine using fluorescein as an internal standard. Compound I, a prodrug
Serife Saçmaci et al.
Analytica chimica acta, 623(1), 46-52 (2008-07-10)
A method for speciation, preconcentration and separation of Fe(II) and Fe(III) in different matrices was developed using solvent extraction and flame atomic absorption spectrometry. 4-Acetyl-5-methyl-1-phenyl-1H-pyrazole-3-carboxylic acid (AMPC) was used as a new complexing reagent for Fe(III). The Fe(III)-AMPC complex was
Sebastian L Riedel et al.
Biotechnology and bioengineering, 110(2), 461-470 (2012-08-21)
Reduced downstream costs, together with high purity recovery of polyhydroxyalkanoate (PHA), will accelerate the commercialization of high quality PHA-based products. In this work, a process was designed for effective recovery of the copolymer poly(hydroxybutyrate-co-hydroxyhexanoate) (P(HB-co-HHx)) containing high levels of HHx

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