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Merck

1.09114

Potassium hydroxide solution

c(KOH) = 0.5 mol/l (0.5 N), in ethanol, reag. Ph. Eur., ready-to-use volumetric solution for titration in non-aqueous media, Titripur®

別名:

Potassium hydroxide ethanol solution

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この商品について

UNSPSC Code:
12352305
NACRES:
NA.21
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製品名

Potassium hydroxide solution in ethanol, c(KOH) = 0.5 mol/l (0.5 N), Titripur®, reag. Ph. Eur.

agency

reag. Ph. Eur.

Quality Level

vapor pressure

59 hPa ( 20 °C)

product line

Titripur®

form

liquid

autoignition temp.

425 °C (ethanol)

quality

Analyzed in our ISO 17025 accredited QC lab

expl. lim.

3.5-15.0 % (v/v) ethanol()

reaction suitability

reaction type: Acid-base reactions

concentration

0.5 M

technique(s)

titration: suitable

pH

14 (20 °C in H2O)

bp

78.3 °C/1013 hPa (ethanol)

mp

-114.5 °C (ethanol)

transition temp

flash point 12 °C (ethanol)

density

0.85 g/cm3 at 20 °C

storage temp.

15-25°C

Application


  • Voltammetric Determination: Potassium hydroxide solution in ethanol is used in voltammetric determination of antioxidants in various matrices. A recent study demonstrated its application in the voltammetric determination of the antioxidant 2,6-di-tert-butyl-p-cresol (T501) in transformer oil using a graphite electrode. This method enhances the sensitivity and accuracy of antioxidant detection, crucial for ensuring the stability and performance of oils and other industrial fluids (Zhou et al., Analytical Letters, 2021).

Features and Benefits

Accreditation:
This volumetric solution is analyzed by our calibration laboratory D-K-15185-01-00 which is accredited according to DIN EN ISO/IEC 17025 for analysis of amount-of-substance concentrations in volumetric solutions by DAkkS (Deutsche Akkreditierungsstelle - German National Accreditation Body). The accreditation certificate can be found at www.sigmaaldrich.com/ISO17025.

Packaging

SKU-pack size numbers ending with a "3" are SmartChemicals with an RFID tag on the label for seamless data transfer to the instrument, e.g. xxxxxx1003 or xxxxxxx 4003. More information on www.sigmaaldrich.com/SmartChemicals

Analysis Note

Form liquid
Amount-of-substance concentration 0.4975 - 0.5025 mol/L
Measurement uncertainty ± 0.0015 mol/L
Traceability NIST SRM

The concentration is determined by volumetric titration and refers to 20°C.
The amount-of-substance concentration of this volumetric solution is traceable to a primary standard reference material (SRM) from the National Institute of Standards and Technology, Gaithersburg, USA (NIST SRM 350 benzoic acid) by means of volumetric standard benzoic acid (article number 1.02401), certified reference material according to ISO 17034, analyzed by our accredited calibration laboratory of Merck KGaA, Darmstadt, Germany according to DIN EN ISO/IEC 17025. The uncertainty is expressed as expanded measurement uncertainty with a coverage factor k=2 covering a confidence level of 95%.

Note: The titer is a correction factor to correct for variations of the volumetric solution, the titration equipment, the temperature and other laboratory conditions. For correct titration results it is recommended to determine a titer with the laboratory specific equipment and under laboratory specific conditions directly after opening a new bottle and at regular time intervals.

Legal Information

Titripur is a registered trademark of Merck KGaA, Darmstadt, Germany


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Danger

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1B

保管分類

3 - Flammable liquids

wgk

WGK 1

flash_point_f

53.6 °F - closed cup - (ethanol)

flash_point_c

12 °C - closed cup - (ethanol)


適用法令

試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

1091141000:4548174003787 + 1091140000: + 1091142500: + 1091141003:

jan

Group 4: Flammable liquids + Alcohols + Hazardous rank II

fsl



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グローバルトレードアイテム番号

カタログ番号GTIN
1.09114.100004022536110745
1.09114.100304054839533679