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Merck

50439

過塩素酸濃縮溶液

0.01 M HClO4 in water (0.01N), eluent for IC

別名:

過塩素酸 溶液

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この商品について

化学式:
HClO4
CAS番号:
分子量:
100.46
NACRES:
NB.21
PubChem Substance ID:
UNSPSC Code:
12161700
MDL number:
Concentration:
0.01 M HClO4 in water (0.01N)
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Quality Level

concentration

0.01 M HClO4 in water (0.01N)

technique(s)

ion chromatography: suitable

SMILES string

OCl(=O)(=O)=O

InChI

1S/ClHO4/c2-1(3,4)5/h(H,2,3,4,5)

InChI key

VLTRZXGMWDSKGL-UHFFFAOYSA-N

General description

This eluent for ion chromatography is determined by potentiometric titration. Content and expiry date can be found on the certificate.

Application

Metrohm IC Application note AN-O-039 :Organic acids in samples from biogas production by ion-exclusion chromatography after dialysis

Metrohm IC Application note AN-O-040 :Borate in seawater

Metrohm IC Application note AN-S-281 :Inorganic and organic anions in wine applying Inline Ultrafiltration

Preparation Note

Prepared with perchloric acid and high purity water (18.2 MΩ, 0.2 μm filtered)

Other Notes

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保管分類

12 - Non Combustible Liquids

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves



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He-Ping Zhao et al.
Environmental science & technology, 47(3), 1565-1572 (2013-01-10)
We evaluated a strategy for achieving complete reduction of perchlorate (ClO(4)(-)) in the presence of much higher concentrations of sulfate (SO(4)(2-)) and nitrate (NO(3)(-)) in a hydrogen-based membrane biofilm reactor (MBfR). Full ClO(4)(-) reduction was achieved by using a two-stage
Dipanwita Das et al.
Journal of the American Chemical Society, 135(10), 4018-4026 (2013-02-28)
Catalytic four-electron reduction of O2 by ferrocene (Fc) and 1,1'-dimethylferrocene (Me2Fc) occurs efficiently with a dinuclear copper(II) complex [Cu(II)2(XYLO)(OH)](2+) (1), where XYLO is a m-xylene-linked bis[(2-(2-pyridyl)ethyl)amine] dinucleating ligand with copper-bridging phenolate moiety], in the presence of perchloric acid (HClO4) in
Dipanwita Das et al.
Journal of the American Chemical Society, 135(7), 2825-2834 (2013-02-12)
Selective two-electron plus two-proton (2e(-)/2H(+)) reduction of O(2) to hydrogen peroxide by ferrocene (Fc) or 1,1'-dimethylferrocene (Me(2)Fc) in the presence of perchloric acid is catalyzed efficiently by a mononuclear copper(II) complex, [Cu(II)(tepa)](2+) (1; tepa = tris[2-(2-pyridyl)ethyl]amine) in acetone. The E(1/2)