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A propos de cet article
Formule linéaire :
LiClO4
Numéro CAS:
Poids moléculaire :
106.39
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
EC Number:
232-237-2
MDL number:
Assay:
99.99% trace metals basis
Form:
powder and chunks
Solubility:
H2O: 106.4 g/L at 20 °C
Service technique
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99.99% trace metals basis
form
powder and chunks
reaction suitability
core: lithium, reagent type: oxidant
greener alternative product characteristics
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
236 °C (lit.)
solubility
H2O: 106.4 g/L at 20 °C
application(s)
battery manufacturing
greener alternative category
SMILES string
[Li+].[O-]Cl(=O)(=O)=O
InChI
1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
InChI key
MHCFAGZWMAWTNR-UHFFFAOYSA-M
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.
Lithium perchlorate (LiClO4) is a neutral salt with high solubility. LiClO4 finds use as an electrolyte for lithium-sulfur batteries; it has been shown to give rise to the effective inhibition of the chemical polysulfide shuttle which subsequently boosts the columbic efficiency through the charge process.
Lithium percholate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
Application
LiClO4 can be used as an additive in the preparation of high-performance polyvinylidene fluoride (PVDF) fibrous membranes. It can also be doped with chitosan and starch for the fabrication of supercapacitors.
LiClO4 is used as an electrolyte salt for lithium-sulfur batteries. LiClO4 acts as a catalyst in the solvent free thiolysis of epoxides. It has been used in various organic transformations.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3
target_organs
Respiratory system
Classe de stockage
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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Preparation of porous PVDF hollow fibre membrane via a phase inversion method using lithium perchlorate (LiClO4) as an additive
Yeow ML, et al.
Journal of Membrane Science , 258(1-2), 16-22 (2005)
Shuttle inhibitor effect of lithium perchlorate as an electrolyte salt for lithium-sulfur batteries
Kim HS, et al.
J. Appl. Electrochem., 42(2) (2012)
Lithium perchlorate doped plasticized chitosan and starch blend as biodegradable polymer electrolyte for supercapacitors
Sudhakar YN and Selvakumar M
Electrochimica Acta, 78, 398-405 (2012)


