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Merck

667420

1H,1H,2H,2H-Perfluorooctyltriethoxysilane

98%

Synonyme(s) :

Triethoxy(1H,1H,2H,2H-perfluoro-1-octyl)silane, Triethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-octyl)silane

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A propos de cet article

Formule empirique (notation de Hill) :
C14H19F13O3Si
Numéro CAS:
Poids moléculaire :
510.36
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
257-473-3
MDL number:
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InChI key

AVYKQOAMZCAHRG-UHFFFAOYSA-N

InChI

1S/C14H19F13O3Si/c1-4-28-31(29-5-2,30-6-3)8-7-9(15,16)10(17,18)11(19,20)12(21,22)13(23,24)14(25,26)27/h4-8H2,1-3H3

SMILES string

CCO[Si](CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)(OCC)OCC

assay

98%

Quality Level

refractive index

n20/D 1.344

density

1.3299 g/mL at 25 °C

General description

1H,1H,2H,2H-Perfluorooctyltriethoxysilane(FOTS) is a fluorinated alkyl silane that is majorly used for improving the wettability of the substrate by lowering the surface energy. It facilitates a superhydrophobic coating by enriching the surface with CF3 group and a water contact angle above 150°.
Triethoxy(1H,1H,2H,2H-perfluoro-1-octyl)silane (POTS) is a fluorine based polymer. POTS possesses low surface free energy leading to its anti-adhesive behavior to polar and non-polar substances. It shows very good weathering stability on account of the carbon- fluorine bond. POTS hydrolyzes in wet environment to form silane based film and self healing anticorrosive polymers, the film formed from the hydrolysis and polycondensation of POTS and water is hydrophobic in nature. This wetting property acts in repelling aqueous electrolyte solution away from metallic substrates and hence providing corrosion protection to metal substrate.

Application

POTS can be used as a silane based coating on poly(vinylidene fluoride) (PVDF) to synthesize a membrane for the removal of hazardous volatile organic compounds. Glass substrates can be modified with POTS to increase the contact angle for 3D reactive inkjet printing of polydimethylsiloxane (PDMS). It can also be used in the synthesis of superhydrophobic carbon nanotubes(CNT) hollow membranes for membrane desalination (MD) as eco-friendly products of fresh water. It is deposited on the roughened surface of titanium to render it superhydrophobic. POTS may be used as a component of fluorine modified ORMOCER (Organically Modified Ceramics) coating materials.

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Hazard Classifications

Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Classe de stockage

10 - Combustible liquids

wgk

WGK 1

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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3D reactive inkjet printing of polydimethylsiloxane.
Sturgess C, et al.
Journal of Material Chemistry C, 5(37), 9733-9743 (2017)
Tian Li et al.
Science (New York, N.Y.), 364(6442), 760-763 (2019-05-28)
Reducing human reliance on energy-inefficient cooling methods such as air conditioning would have a large impact on the global energy landscape. By a process of complete delignification and densification of wood, we developed a structural material with a mechanical strength
Enhancing membrane performance in removal of hazardous VOCs from water by modified fluorinated PVDF porous material.
Al-Gharabli S, et al.
Journal of Membrane Science , 556, 214-226 (2018)
Lin Wang et al.
Science advances, 6(29), eabb2307-eabb2307 (2020-08-25)
Many natural surfaces are capable of rapidly shedding water droplets-a phenomenon that has been attributed to the presence of low solid fraction textures (Φs ~ 0.01). However, recent observations revealed the presence of unusually high solid fraction nanoscale textures (Φs
Zhongshun Wang et al.
Nanoscale, 9(43), 16749-16754 (2017-10-27)
The performance of surface-enhanced Raman scattering (SERS) for detecting trace amounts of analytes depends highly on the enrichment of the diluted analytes into a small region that can be detected. A super-hydrophobic delivery (SHD) process is an excellent process to

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