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Merck

38213

Allura Red AC

analytical standard

Synonyme(s) :

Disodium 6-hydroxy-5-[(2-methoxy-5-methyl-4-sulfophenyl)azo]-2-naphthalenesulfonate

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A propos de cet article

Formule empirique (notation de Hill) :
C18H14N2Na2O8S2
Numéro CAS:
Poids moléculaire :
496.42
NACRES:
NA.24
E Number:
E129
PubChem Substance ID:
UNSPSC Code:
12164500
EC Number:
247-368-0
MDL number:
Colour Index Number:
16035
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InChI

1S/C18H16N2O8S2.2Na/c1-10-7-14(16(28-2)9-17(10)30(25,26)27)19-20-18-13-5-4-12(29(22,23)24)8-11(13)3-6-15(18)21;;/h3-9,21H,1-2H3,(H,22,23,24)(H,25,26,27);;/q;2*+1/p-2/b20-19+;;

InChI key

CEZCCHQBSQPRMU-LLIZZRELSA-L

SMILES string

[Na+].[Na+].COc1cc(c(C)cc1\N=N\c2c(O)ccc3cc(ccc23)S([O-])(=O)=O)S([O-])(=O)=O

grade

analytical standard

assay

≥98.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

mp

>300 °C (lit.)

application(s)

cleaning products
cosmetics
food and beverages
personal care

format

neat

Quality Level

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General description

Allura red AC (E29) is a mono azo dye, added as a synthetic colorant to various drinks, juices, bakery, meat, and sweets products. It has been approved for use as a food additive by European Union (EU) Register as per Annex I of Directive 94/36/EC. The USA Food and Drug Administration (FDA) has approved its use in food, drugs, and cosmetics as a substitution for amaranth (Red 2) and erythrosine (Red 3). It is commonly known as Food Red No. 40 and Food, Drug, and Cosmetics Red No. 40 (FD&C Red No. 40).

This substance belongs to the class of azo dyes. Find here a comprehensive listingof all our food colorant reference materials.

Application

The analytical standards can also be used as follows:
  • Hydrophobic deep eutectic solvents (HDES) based liquid-phase microextraction (LPME) of Allura Red AC and tartrazine in food samples for their quantification by UV-Vis spectrophotometry
  • Nanomolar-level determination of Allura red in soft drink powder samples using a voltammetric electrochemical sensor based on a glassy carbon electrode (GCE) modified with cross-linked chitosan film incorporated with carbon black particles and ionic liquid,1 -butyl-3-methylimidazolium tetrafluoroborate
  • Simultaneous analysis of Sunset Yellow FCF, Allura Red AC, Quinoline Yellow WS, and Tartrazine in gummy bears, chewing gum, and sweet candy samples by reversed phase-high-performance liquid chromatography (RP-HPLC) coupled with UV detection
  • Construction of an electrochemical sensor based on cobalt complex decorated carbon paste electrode (CoC/CPE) for the cyclic voltametric determination of tartrazine, sunset yellow, and Allura red in gelatin and pharmaceutical dosages of acetaminophen
  • Multi-residue analysis of 20 synthetic dyes in 18 chili powders and six syrup-preserved fruit samples by liquid chromatography-tandem mass spectrometry (LC-MS/MS)

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

Classe de stockage

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable


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Consulter la Bibliothèque de documents

Compendium of Food Additive Specifications: Combined Specifications from 1st Through the 37th Meetings.
Dr.Kenji Ishii
Science, 35-37 (1990)
Spectroscopic characterization of SC-NTR: A subsidiary dye of Allura Red AC dye (FD&C Red No. 40).
Yuiko T
Food Additives and Contaminants, 11 (1), 97-104 (1994)
B Fallico et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 28(11), 1501-1515 (2011-08-23)
This article reports the results of a survey and an exposure study, based on a probabilistic approach, concerning red juice-based and red soft drink products in Italy. It highlights the fact that the estimates of both the consumption rates and
Reyna G Sánchez-Duarte et al.
Water science and technology : a journal of the International Association on Water Pollution Research, 65(4), 618-623 (2012-01-27)
The present study was designed to evaluate the chitosan, which has been obtained by deacetylation of chitin, as a biosorbent. The chitin was isolated from fermented shrimp waste by an important local industrial food biopolymer. The aim of this work
Ahmad H Alghamdi
Journal of AOAC International, 88(5), 1387-1393 (2006-01-03)
Square wave (SW) voltammetry was used to explore the adsorption properties of the food additive dye Allura Red on a hanging mercury drop electrode (HMDE). By using the adsorptive stripping voltammetric approach, we developed a sensitive electroanalytical method for the

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