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818308 (-)-Brucine

818308
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Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
357-57-3206-614-7C₂₃H₂₆N₂O₄394.47 g/mol

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8183080050
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      Description
      Catalogue Number818308
      Synonyms2,3-Dimethoxy strychnine
      References
      Product Information
      CAS number357-57-3
      EC index number614-006-00-1
      EC number206-614-7
      Hill FormulaC₂₃H₂₆N₂O₄
      Molar Mass394.47 g/mol
      HS Code2939 79 90
      Structure formula ImageStructure formula Image
      Quality LevelMQ200
      Applications
      Application(-)-Brucine for resolution of racemates for synthesis. CAS 357-57-3, molar mass 394.47 g/mol.
      Biological Information
      Physicochemical Information
      Melting Point175 - 178 °C
      Bulk density230 kg/m3
      Solubility3.2 g/l slightly soluble
      Dimensions
      Materials Information
      Toxicological Information
      Safety Information according to GHS
      Hazard Pictogram(s) Hazard Pictogram(s)
      Hazard Statement(s)H300 + H330: Fatal if swallowed or if inhaled.
      H412: Harmful to aquatic life with long lasting effects.
      Precautionary Statement(s)P273: Avoid release to the environment.
      P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
      P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
      Signal WordDanger
      RTECSEH8925000
      Storage class6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
      WGKWGK 3 highly hazardous to water
      Disposal9
      Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
      Safety Information
      Hazard Symbols Hazard SymbolsVery toxic
      Categories of dangervery toxic, dangerous for the environment
      R PhraseR 26/28-52/53
      Very toxic by inhalation and if swallowed.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
      S PhraseS 13-45-61
      Keep away from food, drink and animal feedingstuffs.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.
      Product Usage Statements
      Storage and Shipping Information
      StorageStore below +30°C.
      Packaging Information
      Transport Information
      Declaration (railroad and road) ADR, RIDUN 1570 , 6.1, I
      Declaration (transport by air) IATA-DGRUN 1570 , 6.1, I
      Declaration (transport by sea) IMDG-CodeUN 1570 , 6.1, I
      Supplemental Information
      Specifications
      Assay (HClO₄)≥ 98.0 %
      Melting range (lower value)≥ 173 °C
      Melting range (upper value)≤ 178 °C
      Spec. rotation [α²0/D (c=1 in ethanol)-86.0 - -80.0 °
      Identity (IR)passes test

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      Categories

      Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Phenols and Phenol Ethers > Phenolcarboxylic Acids and Derivatives
      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Products for Enantioselective Synthesis > Reagents for Resolving Racemates
      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Phenols and Phenol Ethers > Phenolcarboxylic Acids and Derivatives
      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Phenols and Phenol Ethers > Phenolcarboxylic Acids and Derivatives
      Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reagents for Enantioselective Synthesis > Reagents for Resolving Racemates
      Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Reagents for Enantioselective Synthesis > Reagents for Resolving Racemates