130079
メチルトリフェニルホスホニウムブロミド
98%
別名:
TPMP, Triphenylmethylphosphonium bromide, triphenylmethylphosphonium bromide
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この商品について
化学式:
CH3P(C6H5)3Br
CAS番号:
分子量:
357.22
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-218-9
Beilstein/REAXYS Number:
3599467
MDL number:
Assay:
98%
Form:
powder
InChI key
LSEFCHWGJNHZNT-UHFFFAOYSA-M
InChI
1S/C19H18P.BrH/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1
SMILES string
[Br-].C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
assay
98%
form
powder
reaction suitability
reaction type: C-C Bond Formation
mp
230-234 °C (lit.)
functional group
phosphine
Quality Level
関連するカテゴリー
Application
Wittig反応によるメチレン化反応に広く用いられています。
ベンゾアゼピン環系を生成する閉環メタセシスの基質となるエンインの合成に最近用いられたWittigオレフィン化塩です。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Chronic 2
wgk
WGK 3
flash_point_f
>464.0 °F
flash_point_c
> 240 °C
ppe
dust mask type N95 (US), Eyeshields, Gloves
保管分類
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
130079-BULK: + 130079-25G: + 130079-10KG: + 130079-VAR: + 130079-100G: + 130079-500G:
jan
V Borutaite et al.
Biochimica et biophysica acta, 1272(3), 154-158 (1995-12-12)
We investigated the effects of ischemia on the kinetics and control of mitochondria isolated from normal and ischemic heart. The dependence of the respiratory chain, phosphorylation system and proton leak on the mitochondrial membrane potential were measured in mitochondria from
L Calzada et al.
Archives of andrology, 38(2), 151-155 (1997-03-01)
Membrane potential across the plasma membrane (psi) of human sperm was determined by measuring the accumulation of triphenylmethylphosphonium (TPMP+). Washed sperm of fertile or infertile men were suspended, incubated in low-K+ and high-Na+ or high-K+ and low-Na+ medium, and allowed
Duncan G G McMillan et al.
The Journal of biological chemistry, 282(24), 17395-17404 (2007-04-17)
Analysis of the atp operon from the thermoalkaliphilic Bacillus sp. TA2.A1 and comparison with other atp operons from alkaliphilic bacteria reveals the presence of a conserved lysine residue at position 180 (Bacillus sp. TA2.A1 numbering) within the a subunit of
M P Murphy
Expert opinion on biological therapy, 1(5), 753-764 (2001-12-01)
Mitochondrial dysfunction causes or exacerbates a number of diseases. These include genetic disorders such as Friedreich's ataxia where the primary lesion is a defect in a nuclear gene and those diseases caused by mutations to mitochondrial DNA. Mitochondrial damage also
Meredith F Ross et al.
The Biochemical journal, 411(3), 633-645 (2008-02-26)
Mitochondria-targeted molecules comprising the lipophilic TPP (triphenylphosphonium) cation covalently linked to a hydrophobic bioactive moiety are used to modify and probe mitochondria in cells and in vivo. However, it is unclear how hydrophobicity affects the rate and extent of their
ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.
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