394440
ヒドラジン 一臭化水素酸塩
≥98%
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この商品について
化学式:
H2NNH2 · HBr
CAS番号:
分子量:
112.96
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
237-412-7
MDL number:
Assay:
≥98%
Form:
solid
Quality Segment
assay
≥98%
form
solid
mp
87-92 °C (lit.)
SMILES string
Br.NN
InChI
1S/BrH.H4N2/c;1-2/h1H;1-2H2
InChI key
DVHXJLRODLTJOD-UHFFFAOYSA-N
General description
Hydrazine monohydrobromide (hydrazinium bromide) is a hydrobromide salt of hydrazine. It has been prepared by adding aqueous hydrobromic acid to aqueous hydrazine. Its crystal structure has been investigated. It participates in the synthesis of 2-(2′-furoyl)-4(5)-(2′-furanyl)-1H-imidazole (FFI). It is formed as an intermediate during the formation of phosphaminimides from hydrazide derivatives. The fumes from the pyrolysis of hydrazine monohydrobromide soldering flux have been reported to cause dermatitis.
Application
Hydrazine monohydrobromide (hydrazinium bromide) may be used in the synthesis of bromostannates and bromostannites by reacting with tin bromide and also in soldering flux.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Skin Sens. 1
保管分類
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
第5類:自己反応性物質 + ヒドラジンの誘導体 + 危険等級I + 第一種自己反応性物質
fsl
Protection of workers against dermatitis on exposure to hydrazine hydrobromide soldering flux.
Cook WA
International Archives of Occupational and Environmental Health, 13(6), 616-618 (1955)
A Facile Synthesis of an Advanced Glycosylation Endproduct 2-(2'-furoyl)-4 (5)-(2'-furanyl)-1 H-imidazole.
Rho T, et al
Synthetic Communications, 27(24), 4315-4318 (1997)
504. Hydrazine. Part IV. The bromostannates and bromostannites of hydrazine, dimethyl ketazine, and pentan-3-one hydrazone.
Pugh, W
Journal of the Chemical Society, 2491-2493 (1953)