コンテンツへスキップ
Merck

919977

ビス(トリフルオロメタン)スルホンイミド リチウム塩

greener alternative

99.99% trace metals basis

別名:

ビス(トリフルオロメチルスルホニル)アミン リチウム塩, ビストリフルオロメタンスルホンイミド酸リチウム

ログインで組織・契約価格をご覧ください。

サイズを選択してください

表示を変更する

この商品について

化学式:
CF3SO2NLiSO2CF3
CAS番号:
分子量:
287.09
NACRES:
NA.23
UNSPSC Code:
12352111
Beilstein/REAXYS Number:
6625414
MDL number:
Assay:
99.99% trace metals basis
テクニカルサービス
お困りのことがあれば、経験豊富なテクニカルサービスチームがお客様をサポートします。
お手伝いします


Quality Segment

assay

99.99% trace metals basis

reaction suitability

core: lithium

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

234-238 °C (lit.)

application(s)

battery precursors
catalysts
material synthesis precursor

greener alternative category

SMILES string

[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

InChI

1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

InChI key

QSZMZKBZAYQGRS-UHFFFAOYSA-N

General description

Lithiumbis(trifluoromethanesulfonyl)imide (LiTFSI) is an anhydrous lithium salt known for its hydrophilic properties and excellent solubility in water. LiTFSI is often used as an electrolyte salt in lithium-ion batteries and other electrochemical energy storage systems. It helps improve the electrolyte′s conductivity, stability, and safety, thereby enhancing the overall performance of the battery. The hydrophilic nature of LiTFSI enables effective ion transport and enhances the overall electrochemical properties of batteriesProperties of LiTFSI:
  • High electrochemical stability
  • High lithium-ion conductivity
  • Thermal stability
  • Hydrophilic nature
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

Application

Lithium bis(trifluoromethanesulfonyl)imide can be used as:
  • An additive in the development of dual-functional separator coating materials. These materials are based on covalent organic frameworks (COFs) and are specifically designed for use in high-performance lithium-selenium sulfide batteries. The Li-SeS2 battery achieved outstanding performance in terms of energy storage and stability. It exhibited a specific capacity of 844.6 mA h g-1 at 0.5C and a SeS2 loading of 2 mg cm-2.
  • As an additive in the electrolyte formulation along with polyethylene oxide for the development of solid-state lithium batteries. LiTFSI enhance the ionic conductivity of the PEO-based electrolyte, which is essential for the efficient transport of lithium ions.
  • As a key component in the development of a PEO/LiTFSI-coated polypropylene membrane. This membrane is designed for high-loading lithium–sulfur batteries to enhance battery performance, improve capacity, and extend cycle life.
  • As a component in the electrolyte system along with TEMPOL derivatives. The incorporation of LiTFSI in the electrolyte system enhances the stability and achieves an efficiency of 6.16% in solid-state fiber dye-sensitized solar cells.



signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral

target_organs

Nervous system

保管分類

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable


適用法令

試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。

名称等を表示すべき危険物及び有害物

ishl_indicated

名称等を通知すべき危険物及び有害物

ishl_notified

919977-50G:4.548173380612E12 + 919977-10G:4.548173380605E12

jan



最新バージョンのいずれかを選択してください:

試験成績書(COA)

Lot/Batch Number

適切なバージョンが見つかりませんか。

特定のバージョンが必要な場合は、ロット番号またはバッチ番号で特定の証明書を検索できます。

以前この製品を購入いただいたことがある場合

文書ライブラリで、最近購入した製品の文書を検索できます。

文書ライブラリにアクセスする


資料

シグマアルドリッチでは、MUアイオニックソリューションズ(MUIS、旧宇部興産)製のリチウムイオン電池用高純度電解液、溶媒、添加剤を販売しています。

メルクのSpiro-MeOTAD製品「SHT-263 Solarpur®」は、世界中で広く使用されているペロブスカイト太陽電池用正孔輸送材料です。


Spherical ordered mesoporous carbon nanoparticles with high porosity for lithium-sulfur batteries.
Jörg Schuster et al.
Angewandte Chemie (International ed. in English), 51(15), 3591-3595 (2012-03-03)
Qi Chen et al.
Journal of the American Chemical Society, 136(2), 622-625 (2013-12-24)
Hybrid organic/inorganic perovskites (e.g., CH3NH3PbI3) as light absorbers are promising players in the field of third-generation photovoltaics. Here we demonstrate a low-temperature vapor-assisted solution process to construct polycrystalline perovskite thin films with full surface coverage, small surface roughness, and grain
Namyoung Ahn et al.
Journal of the American Chemical Society, 137(27), 8696-8699 (2015-07-01)
High efficiency perovskite solar cells were fabricated reproducibly via Lewis base adduct of lead(II) iodide. PbI2 was dissolved in N,N-dimethyformamide with equimolar N,N-dimethyl sulfoxide (DMSO) and CH3NH3I. Stretching vibration of S═O appeared at 1045 cm(-1) for bare DMSO, which was