C0267
2-クロロアセトアミド
≥98%
別名:
Chloracetamide, alpha-Chloroacetamide
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この商品について
化学式:
ClCH2CONH2
CAS番号:
分子量:
93.51
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-174-2
Beilstein/REAXYS Number:
878191
MDL number:
製品名
2-クロロアセトアミド, ≥98%
InChI
1S/C2H4ClNO/c3-1-2(4)5/h1H2,(H2,4,5)
InChI key
VXIVSQZSERGHQP-UHFFFAOYSA-N
SMILES string
NC(=O)CCl
vapor pressure
0.05 mmHg ( 20 °C)
assay
≥98%
form
powder
mp
116-118 °C (lit.)
Quality Level
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関連するカテゴリー
Application
2-クロロアセトアミドは、次のような合成で反応体として使用できます：
- 4-クロロ-1H-キノリン-2-オンのo-アルキル化とそれに続くスマイルス転位による2-アミノ-4-クロロキノリン類の合成
- 塩基としての炭酸カリウムの存在下でのヒドロキシベンズアルデヒドとの反応による2-(ホルミルアリロキシ)アセトアミドの合成
- アルミニウムトリフレートを触媒として用いるベンズヒドロールの直接アミノ化によるビアリールアミン誘導体の合成
General description
2-クロロアセトアミドは、別名α-クロロアセトアミドとも呼ばれ、アミドやチオアミドの合成に前駆体として一般的に使用される塩素化有機化合物です。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Repr. 2 - Skin Sens. 1
保管分類
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 2
flash_point_f
338.0 °F
flash_point_c
170 °C
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Jun Zhang et al.
Journal of agricultural and food chemistry, 59(9), 4614-4621 (2011-03-23)
A butachlor-degrading strain, designated FLY-8, was isolated from rice field soil and was identified as Paracoccus sp. Strain FLY-8 could degrade and utilize six chloroacetamide herbicides as carbon sources for growth, and the degradation rates followed the order alachlor >
Cleonice Rocha et al.
Environmental pollution (Barking, Essex : 1987), 152(1), 239-244 (2007-07-17)
Solid-phase microextraction coupled with gas chromatography-mass spectrometry (SPME-GC-MS) was used to analyze two triazine (atrazine and simazine) and three chloroacetamide herbicides (acetochlor, alachlor, and metolachlor) in water samples from a midwest US agricultural drainage ditch for two growing seasons. The
K Eszter Borbas et al.
Bioconjugate chemistry, 18(4), 1205-1212 (2007-06-23)
Targeted radiopharmaceuticals offer the possibility of improved tumor imaging and radiotherapy, with reduced side effects. A variety of monoclonal antibodies and antibody fragments have previously been successfully radiolabeled and used in diagnostic imaging and targeted radiotherapy of cancer. Many such
Ezgi Odabasi et al.
EMBO reports, 20(6) (2019-04-27)
Centriolar satellites are ubiquitous in vertebrate cells. They have recently emerged as key regulators of centrosome/cilium biogenesis, and their mutations are linked to ciliopathies. However, their precise functions and mechanisms of action remain poorly understood. Here, we generated a kidney
Michelle L Hladik et al.
Environmental science & technology, 39(17), 6561-6574 (2005-09-30)
Although laboratory studies have revealed that many different neutral degradates of chloroacetamide herbicides can form during thermochemical, biological, and photochemical transformations, relatively few have been sought in the environment, despite their likely generation in appreciable amounts, relative persistence, and known
資料
Rapid trypsin digest kit yields reliable results in less than 2 hours for mass spectrometry analysis.
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