82270
1,2-ジクロロプロパン
99%
別名:
二塩化プロピレン
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この商品について
化学式:
CH3CHClCH2Cl
CAS番号:
分子量:
112.99
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-152-2
Beilstein/REAXYS Number:
1718880
MDL number:
Assay:
99%
Form:
liquid
InChI key
KNKRKFALVUDBJE-UHFFFAOYSA-N
InChI
1S/C3H6Cl2/c1-3(5)2-4/h3H,2H2,1H3
SMILES string
CC(Cl)CCl
vapor density
3.89 (vs air)
vapor pressure
40 mmHg ( 19.4 °C)
assay
99%
form
liquid
autoignition temp.
1035 °F
expl. lim.
14.5 %
Quality Level
refractive index
n20/D 1.439
bp
95-96 °C (lit.)
mp
−100 °C (lit.)
density
1.156 g/mL at 25 °C (lit.)
functional group
chloro
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関連するカテゴリー
General description
1,2-Dichloropropane, also known as Propylene dichloride, is a chlorinated solvent, that is commonly utilized as an intermediate in the synthesis of basic organic chemicals.
Application
1,2-Dichloropropane can be used as a building block to synthesize:
- 2-Ylidene-1,3-dithiolane derivatives via one-pot reaction with carbon disulfide and active methylene compounds in the presence of sodium ethylate.
- β-Chloropropylsulfurs by controllable dechloro-coupling reaction with thiols.
- Thiazolidine and 1,3-thiazinane derivatives via [3+2] and [3+3] annulation reaction with β-ketothioamides in the presence of phosphonium ylide as a catalyst.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Flam. Liq. 2
保管分類
3 - Flammable liquids
wgk
WGK 3
flash_point_f
59.0 °F - closed cup
flash_point_c
15.0 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
特定第一種指定化学物質
prtr
第4類:引火性液体 + 第一石油類 + 危険等級II + 非水溶性液体
fsl
名称等を表示すべき危険物及び有害物
ishl_indicated
名称等を通知すべき危険物及び有害物
ishl_notified
82270-250ML:4548173331133 + 82270-BULK: + 82270-1L:4548173331126 + 82270-6X1L: + 82270-VAR:
jan
Monish Arbaz Ansari et al.
Organic & biomolecular chemistry, 17(41), 9151-9162 (2019-10-09)
Phosphonium ylides are being reported here as a catalyst for the formation of thiazolidines and 1,3-thiazinanes from β-ketothioamides (which act as a three atom N, C, and S synthon) with dihaloalkanes via [3 + 2] and [3 + 3] annulations
Synthesis of some 2-ylidene-1, 3-dithiolanes
Lipin KV, et al.
Russ. J. Org. Chem., 53(1), 147-149 (2017)
Divergent Electrolysis for the Controllable Coupling of Thiols with 1, 2-Dichloroethane: a Mild Approach to Sulfide and Sulfoxide
Ling F, et al.
Green Chemistry (2022)
A J Tesoriero et al.
Environmental science & technology, 35(3), 455-461 (2001-05-16)
A shallow aquifer with different redox zones overlain by intensive agricultural activity was monitored for the occurrence of 1,2-dichloropropane (DCP) to assess the fate and origin of this pollutant. DCP was detected more frequently in groundwater samples collected in aerobic
[Dichloropropane poisoning: report of 2 cases].
Ana M Lazo-Torres et al.
Medicina clinica, 124(8), 318-318 (2005-03-10)
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