86863
テトラブチルアンモニウムヒドロキシド 溶液
53.5-56.5% in H₂O, soltuion
別名:
N,N,N-Tributyl-1-butanaminium hydroxide, TBAH 40, Tetra-n-butylammonium hydroxide
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この商品について
化学式:
(CH3CH2CH2CH2)4N(OH)
CAS番号:
分子量:
259.47
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Beilstein/REAXYS Number:
3571228
Concentration:
53.5-56.5% in H2O
Form:
liquid
製品名
テトラブチルアンモニウムヒドロキシド 溶液, 53.5-56.5% in H2O
form
liquid
Quality Level
reaction suitability
core: ammonium
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
concentration
53.5-56.5% in H2O
impurities
≤0.2% halides (as bromide)
density
0.995 g/cm3
anion traces
sulfate (SO42-): ≤2000 mg/kg
functional group
amine
greener alternative category
SMILES string
[OH-].CCCC[N+](CCCC)(CCCC)CCCC
InChI
1S/C16H36N.H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H2/q+1;/p-1
InChI key
VDZOOKBUILJEDG-UHFFFAOYSA-M
General description
生成物は、H2Oにテトラブチルアンモニウム水酸化物を溶かした53.5～56.5％溶液です。テトラブチルアンモニウムヒドロキシドはヨウ化テトラブチルアンモニウムから合成されています。 無水イソプロピルアルコールに溶解したTBAOHは弱酸の滴定剤として広く用いられています。
Application
テトラブチルアンモニウム水酸化物溶液（TBAOH）は以下の研究で使用されています：
- 室温条件で10 wt%セルロースを溶解するため。
- 1,2,4-オキサジアゾール合成時の触媒として。
- 脂肪酸のTBAOH塩の調製。
Features and Benefits
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an environmentally benign and has been enhanced for catalytic efficiency. Click here for more information.
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Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1
保管分類
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
B B Y Lau et al.
Bioresource technology, 197, 252-259 (2015-09-08)
Aqueous solutions of tetrabutylphosphonium hydroxide have been evaluated as pretreatment media for rice husks, prior to sulphuric acid hydrolysis or cellulase enzymatic hydrolysis. Varying the water:tetrabutylphosphonium hydroxide ratio varied the rate of delignification, as well as silica, lignin and cellulose
Construction of 3, 5-substituted 1, 2, 4-oxadiazole rings triggered by tetrabutylammonium hydroxide: a highly efficient and fluoride-free ring closure reaction of O-acylamidoximes.
Otaka H, et al.
Tetrahedron Letters, 55(5), 979-981 (2014)
Tetrabutylammonium hydroxide as titrant in nonaqueous media.
Harlow GA, et al.
Analytical Chemistry, 28(5), 787-791 (1956)