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855079 DHP HM resin (100-200 mesh)

Novabiochem®

DHP HM resin (100-200 mesh) MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.
CAS #: 9003-70-7
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855079
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Overview

Replacement Information

Key Spec Table

CAS #
9003-70-7

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      8550790005
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          8550790025
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              Description
              Catalogue Number855079
              Replaces01-64-0192
              Brand Family Novabiochem®
              Alternate Names
              • 3,4-Dihydro-2H-pyran-2-yl-methoxymethyl polystyrene (100-200 mesh)
              • Ellman's dihydropyran resin
              Background InformationA highly versatile support for the solid phase immobilization of primary, secondary alcohols [1-11], phenols [12], purines [13], and indoles [14]. Derivatization is effected by treating the support in DCM with an excess of alcohol in the presence of a catalytic amount of pyridinium p-toluenesulfonate. A similar DHP-based support has also been used for the immobilization of tetrazoles [15].

              Release of the product alcohol from the support has been carried out by treating with 95% TFA/5% water [1] and TFA/DCM/EtOH [2, 12]. However, the use of TFA can lead, in some cases, to trifluoroacetate formation. Methods which eliminate this potential side reaction include PPTS/BuOH/DCE [3], TosOH in DCM [16] and TosOH in DCE/BuOH [17].

              The product number for this product was previously 01-64-0192.

              To obtain a certificate of analysis (CoA) of a lot that begins with the letter "A", please select the option in the right hand menu "Request a COA for Lot#s starting with A".
              References
              Product Information
              CAS number9003-70-7
              HS Code3907 29 90
              Structure formula ImageStructure formula Image
              Quality LevelMQ200
              Applications
              Biological Information
              Physicochemical Information
              Dimensions
              Materials Information
              Toxicological Information
              Safety Information according to GHS
              Storage class10 - 13 Other liquids and solids
              WGKWGK 1 slightly hazardous to water
              Safety Information
              Product Usage Statements
              Storage and Shipping Information
              StorageStore at +2°C to +8°C.
              Packaging Information
              Transport Information
              Supplemental Information
              Specifications
              Color (visual)slight yellow to beige
              Appearance of substance (visual)beads
              Loading (determined from the substitution of the Fmoc-Gly-ol loaded resin)0.70 - 1.20 mmol/g
              Swelling Volume (in CH₂Cl₂)lot specific result
              The polymer matrix is copoly (styrene-1% DVB), 100 - 200 mesh
              Global Trade Item Number
              Catalogue Number GTIN
              8550790001 04027269112783
              8550790005 04027269112790
              8550790025 04027269112806

              Documentation

              DHP HM resin (100-200 mesh) SDS

              Title

              Safety Data Sheet (SDS) 

              Citations

              Title
              • [1] L. A. Thompson & J. A. Ellman (1994) Tetrahedron Lett., 35, 9333.
              • [2] O. B. Wallace (1997) Tetrahedron Lett., 38, 4939.
              • [3] G. Liu & J. A. Ellman (1995) J. Org. Chem., 60, 7712.
              • [4] E. K. Kick & J. A. Ellman (1995) J. Med. Chem., 38, 1427.
              • [5] J. S. Koh & J. A. Ellman (1996) J. Org. Chem., 61, 4494.
              • [6] J. Cossy, et al. (2000) Synlett, 3, 409.
              • [7] M. Ramaseshan, et al. (2000) J. Comb. Chem., 2, 615.
              • [8] M. Ramaseshan, et al. (2000) Tetrahedron Lett., 41, 4743.
              • [9] A. Bianco, et al. (2000) J. Org. Chem., 65, 2179.
              • [10] M. Steger, et al. (2001) Bioorg. Med. Chem. Lett., 11, 2537.
              • [11] A. Dahlgren, et al. (2003) Bioorg. Med.Chem. Lett., 11, 827.
              • [12] W. H. Pearson & R. B. Clark (1997) Tetrahedron Lett., 38, 7669.
              • [13] D. A. Nugiel, et al. (1997) J. Org. Chem., 62, 201.
              • [14] A. L. Smith, et al. (1998) Tetrahedron Lett., 39, 8317.
              • [15] S.-E. Yoo, et al. (1997) Tetrahedron Lett., 38, 1203.
              • [16] J. Beythien (Merck Biociences AG), personal communication.
              • [17] M. R. Tremblay, et al. (1999) Bioorg. Med. Chem. Lett., 9, 2827.